20037-61-0Relevant academic research and scientific papers
REACTIONS INVOLVING TRANSITION METALS. XIX. SOME REACTIONS OF PERFLUORONORBORNADIENE WITH LOW VALENT TRANSITION METAL COMPLEXES
Booth, Brian L.,Casey, Sylvia,Haszeldine, Robert N.
, p. 289 - 300 (2007/10/02)
Perfluoronorbornadiene reacts with the compounds to give the adducts and in which one of the double bonds is coordinated to the metal atom.The platinum complex reacts further with to give 2> having both double bonds coordinated to a Pt atom.The carbonylmetal anions -> react to form the mono-substitution products (M = Mn(CO)5, Re(CO)5, Ir(CO)2(PPh3)2, Rh(CO)2(PPh3)2, but the use of an excess of - leads to substitution of one fluorine atom on each of the double bonds.The complex having M = Mn(CO)5 reacts with to afford the derivative >, and the compound where M = Ir(CO)2(PPh3)2 undergoes an oxidative addition reaction with acetyl chloride.Oxidative coupling products have been isolated on UV irradiation of a mixture of perfluoronorbornadiene and 4-CH2=CRCH=CH2)(CO)3> (R = H, Me), and under similar conditions the reaction with Fe(CO)5 affords in very low yield.
