20046-99-5Relevant academic research and scientific papers
Discovery and evaluation of efficient selenazoles with high antifungal activity against candida spp.
??czkowski, Krzysztof Z.,Misiura, Konrad,Biernasiuk, Anna,Malm, Anna
, p. 118 - 127 (2015/04/14)
Synthesis, characterization and investigation of antifungal and antibacterial activities of fourteen 2,4-disubstituted 1,3-selenazoles is presented. Their structures were determined using 1H and 13C NMR, FAB MS and HRMS analyses. Amo
Cyclohexanone selenosemicarbazone: A convenient starting material for the preparation of functionalised selenosemicarbazones and their Pt and Pd complexes
Bippus, Patrick,Molter, Anja,Müller, David,Mohr, Fabian
experimental part, p. 1657 - 1662 (2010/09/05)
The reaction of hydrazine hydrate with KSeCN in acidic aqueous ethanol in the presence of cyclohexanone affords cyclohexanone selenosemicarbazone in good yields. Cyclohexanone selenosemicarbazone was converted into various functionalised selenosemicarbazones by treatment with aldehydes. Salicylaldehyde selenosemicarbazone and its 1,2-naphthyl-derivative were prepared and reacted with some Pd(II) and Pt(II) phosphine complexes to give compounds of the type [M(LSe)(P)] where M = Pt and Pd, LSe is the doubly deprotonated selenosemicarbazone and P a monodentate phosphine. In these complexes the ligands act as tridentate, dianionic [Se-N-O]2- ligands, which was confirmed by single-crystal X-ray diffraction of the Pd derivative.
