20052-58-8Relevant academic research and scientific papers
REGIOSPECIFIC ALKENYLATION OF PHENOLS BY 1,1-DIMETHYLALLENE PROMOTED BY PLATINUM CATALYSTS
Renzi, Augusto De,Panunzi, Achille,Saporito, Antonio,Vitagliano, Aldo
, p. 993 - 996 (2007/10/02)
1,1-Dimethylallene reacts with phenolic substrates in the presence of catalytic amounts of platinum(II) complexes.A regiospecific C-alkenylation takes place, affording o-isopentenylphenols and 2,2-dimethylchromans.Possible reaction mechanisms are also discussed.
Synthesis of 3-Hydroxy-2,3,4,5-tetrahydro-3-methylbenzoxepins by Ring-closure of Isoprenyl Terminal Epoxides
Baird, Kenneth J.,Grundon, Michael F.
, p. 1820 - 1825 (2007/10/02)
Terminal olefins (13), obtained from reactions of tertiary chlorides (10) with triphenylmethyl-lithium, were converted into epoxides (14); base-induced ring-closure of the latter gave 2-hydroxymethyl-2-methylchromans (15) and 3-hydroxy-2,3,4,5-tetrahydro-3-methylbenzoxepins (17).Dehydration of the tetrahydrobenzoxepin (17a) furnished dihydrobenzoxepins.
