20079-30-5Relevant academic research and scientific papers
New efficient Synthesis of Furanoacetylene Phytoalexins Wyerone and Dihydrowyerone
Delamarche, Isabelle,Mosset, Paul
, p. 2465 - 2468 (2007/10/02)
Furanoacetylene phytoalexins wyerone 1a and dihydrowyerone 1b were efficiently synthesized in multigram quantities starting from furfural.The key step involved an acylation by acetylenic N-methoxy-N-methylamides 3a,b. Key words: Phytoalexins, dihydrowyerone, wyerone, N-methoxy-N-methylamides.
Total Syntheses of Wyerone and Dihydrowyerone, Phytoalexins from the Broad Bean, Vicia faba L., using the Dianion derived from 3-(2-Furyl)acrylic Acid
Knight, David W.,Nott, Andrew P.
, p. 623 - 626 (2007/10/02)
Treatment of 3-(2-furyl)acrylic acid (8) with lithium di-isopropylamide at low temperatures gives lithium 3-(5-lithio-2-furyl)acrylate (9).This has been used to prepare the broad bean metabolites wyerone (1) and dihydrowyerone (2) by condensations with (Z
