200942-59-2Relevant academic research and scientific papers
The anion of a phenyltris(alkylamino)phosphonium (PhTAP) salt as a chelating ligand: Synthesis and X-ray crystal structure of a 16-electron ruthenium(II) organometallic complex
Bailey, Philip J.,Grant, Keith J.,Parsons, Simon
, p. 551 - 555 (1998)
The phosphonium salt [PhP(NHiPr)3]Br has been synthesized, and the ligand properties of its deprotonated forms have been investigated. Treatment of its dilithiate Li2[PhP(Ni-Pr)3] with the dimer [(η-p-cymene)RuCl2]2 provides the unsaturated 16-electron cation [(η-p-cymene)Ru{η2-(iPrN)2PPh(NH iPr)}]+ which adds cyanide and carbon monoxide (reversibly) and has been structurally characterized as its tetraphenylborate salt.
