201009-33-8Relevant articles and documents
A short synthesis of conjugated unsaturated alcohols
Kazmaier, Uli
, p. 1491 - 1496 (2007/10/03)
Isomerization of acetylenic pentafluorophenyl esters in the presence of phosphines gives rise to activated dienoic esters, which can be reduced directly in a simple one pot procedure to the corresponding conjugated unsaturated alcohols 6-10. The higher reactivity of the pentafluorophenyl esters in comparison to alkyl esters allows their selective isomerization.