201022-72-2Relevant academic research and scientific papers
Synthesis and characterization of molybdenum(VI)-dioxo complexes containing both coordinated thiolate and carboxylate groups. Reactions with their own free ligands
Li, Hong,Palanca, Pedro,Sanz, Vicent,Picher, M. Teresa,Domingo, Luis R.,Domenech, Antonio,Folgado, Jose-Vicente
, p. 145 - 150 (1998)
The synthesis, characterization and spectroscopic properties of a group of Mo(VI) complexes having thiocarboxylate ligands of type [MoVIO2(O2CC(S)MePh-X)2] 2- have been reported (X = H, p-Me, p-Cl). The peak potential for the Mo(VI) reduction increases according to the electron-donor ability of X (Me > H > Cl). Reaction of these Mo(VI) complexes with their own free ligands has been studied by ESR and UV-Vis spectroscopy, yielding the monomeric [MoVO(O2CC(S)MePh-X)2]- as unique complex products. The kinetic study of this oxidation reaction has also been investigated.
