201025-01-6Relevant academic research and scientific papers
Unsymmetrical ozonolysis of carbohydrate derived norbornene systems
Testero, Sebastián A.,Mangione, María I.,Poeylaut-Palena, Andrés A.,Sierra, Manuel González,Spanevello, Rolando A.
, p. 11410 - 11420 (2008/03/13)
The ozonolysis of carbohydrate derived norbornene systems in participating solvents demonstrated that different remote controlling factors could induce the regioselective fragmentation of the primary ozonide. The exo norbornene series afforded a complete
Enantiospecific approach toward pentalenolactone
Testero, Sebastian A.,Spanevello, Rolando A.
, p. 3793 - 3796 (2007/10/03)
The enantiospecific assembly of the pentalenolactones' carbon skeleton was achieved in 17 steps and 16% overall yield from methyl α-D- glucopyranoside. The synthetic strategy relies on two highly efficient key steps: an exo-diastereoselective Diels Alder
Enantiospecific approach to a quinane skeleton related to pentalenolactones
Pellegrinet, Silvina C.,Spanevello, Rolando A.
, p. 8623 - 8626 (2007/10/03)
A novel and general approach has been delineated for the enantiomerically pure synthesis of the angularly fused tricyclic system of the pentalenolactone family of compounds. D-Glucose is used as starting material and a diasteroselective Diels-Alder reaction sets the elements for the ring junctions.
