201050-00-2Relevant academic research and scientific papers
Intramolecular nucleophilic attack at silicon in o-silylbenzyl alcohols. Generation of allyl and benzyl anion equivalents
Hudrlik, Paul F.,Hudrlik, Anne M.,Jeilani, Yassin A.
scheme or table, p. 10089 - 10096 (2012/02/13)
Substituted silyl ethers of o-bromobenzyl alcohols and the derived o-silylbenzyl alcohols were used to transfer allyl and benzyl groups from silicon to the electrophiles benzaldehyde and benzophenone in excellent yields. γ-Oxidosilane intermediates (and possibly hypercoordinated silicon intermediates) are postulated.
