201163-60-2

Basic information

• Product Name: Ru(CO)4(η(1)-1,6-bis(diphenylphosphino)hexane)
• CAS NO: 201163-60-2
• Molecular Weight: 667.643
• Mol File: 201163-60-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Ru(CO)4(η(1)-1,6-bis(diphenylphosphino)hexane)(CAS DataBase Reference)
• NIST Chemistry Reference: Ru(CO)4(η(1)-1,6-bis(diphenylphosphino)hexane)(201163-60-2)
• EPA Substance Registry System: Ru(CO)4(η(1)-1,6-bis(diphenylphosphino)hexane)(201163-60-2)

Safety Data

• Hazardous Substances Data: 201163-60-2(Hazardous Substances Data)

Upstream product

• 52621-15-5 [Ru(CO)4(η2-ethylene)] 
• 19845-69-3 1,6-bis(diphenylphosphino)hexane 

Relevant articles and documents

The synthesis of novel neutral mononuclear ruthenium fragments for cluster capping reactions and their reactivity

The mononuclear complex [Ru(CO)4(C2H4)] (1) reacts with bidentate phosphines to yield the corresponding [Ru(CO)4(η1-bidentate phosphine)] (3) complex in quantitative yield thereby offering a new route to this class of compound. Broadband UV photolysis of dichloromethane solutions of the 1,2-bis(diphenylphosphino)propane (dppp) complex [Ru(CO)4(η1-dppp)] (3d) under an atmosphere of ethene yields the di-substituted complex [Ru(CO)3(η1-dppp)(η2-C2H4)] (9d) in quantitative yield. Both 3d and 9d show potential in selective cluster capping reactions as illustrated by their reactivity with [Ru5C(CO)15] (4) and [Ru3(CO)12] (2).