201213-22-1

Basic information

• Product Name: Pd(OC₆H₄CHNCH₂C₆H₅)2
• CAS NO: 201213-22-1
• Molecular Weight: 526.931
• Mol File: 201213-22-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pd(OC₆H₄CHNCH₂C₆H₅)2(CAS DataBase Reference)
• NIST Chemistry Reference: Pd(OC₆H₄CHNCH₂C₆H₅)2(201213-22-1)
• EPA Substance Registry System: Pd(OC₆H₄CHNCH₂C₆H₅)2(201213-22-1)

Safety Data

• Hazardous Substances Data: 201213-22-1(Hazardous Substances Data)

Upstream product

• 886-08-8 N-(benzyl)salicylaldimine 
• 3375-31-3 palladium diacetate 

Relevant articles and documents

Bicyclic cyclopalladated complexes derived from N-benzyl-substituted Schiff's bases

2-Benzylamino-2-penten-4-one (Hacac-bn) reacts with Pd(MeCO2)2 and [Pd(MeCO2)2(SPri2)2] in benzene at 50°C to give an N,O-chelated complex, [Pd(acac-bn)2] and a bicyclic cyclopalladated complex, [Pd(acac-NCH2C6H4)(SPri2)], respectively. Diisopropyl sulfide ligand in the latter complex is replaced easily by PPh3, giving [Pd(acac-NCH2C6H4)(PPh3)]. N-(Salicylidene)benzylamine (Hsal-bn) also reacts similarly with Pd(MeCO2)2 and [Pd(MeCO2)2(SPri2)2] at 50°C to afford [Pd(sal-bn)2] and [Pd(sal-NCH2C6H4)(SPri2)], respectively. N-(3,5-Dichlorosalicylidene)benzylamine (Hdcsal-bn) reacts with [Pd(MeCO2)2(SPri2)2] and Pd(MeCO2)2 in the presence of PPh2(OMe) at 50°C to yield cyclopalladated complexes, [Pd(dcsal-NCH2C6H4)(SPri2)] and [Pd(dcsal-NCH2C6H4){PPh2(OMe)}], respectively. [Pd(MeCO2)2(dmpy)2] (dmpy = 3,5-dimethylpyridine) reacted with Hdcsal-bn in 1:1 and 1:2 molar ratios at 50°C to give [Pd(dcsal-bn)(MeCO2)(dmpy)] and [Pd(dcsal-bn)2], respectively. The functions of SPri2 and dmpy in these reactions are discussed.