201232-87-3

Basic information

• Product Name: [4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]benzene
• Synonyms: [4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]benzene
• CAS NO: 201232-87-3
• Molecular Weight: 434.767
• Mol File: 201232-87-3.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: [4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]benzene(201232-87-3)
• EPA Substance Registry System: [4,6-di-O-(tert-butyldimethylsilyl)-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl]benzene(201232-87-3)

Safety Data

• Hazardous Substances Data: 201232-87-3(Hazardous Substances Data)

Upstream product

• 171082-23-8 4-t-butylphenyl4, 6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 
• 201233-15-0 (2R,3S,6R)-6-(4-tert-Butyl-phenoxy)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol 
• 100-58-3 phenylmagnesium bromide 
• 201232-73-7 p-tert-butylphenyl 4,6-di-O-tert-butyl(dimethyl)silyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranoside 

Downstream Products

• 368452-29-3 (2,3-dideoxy-β-D-erythro-hexanopyranosyl)benzene 
• 368452-23-7 (2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)benzene 
• 3682-06-2 (2,3,4,6-tetra-O-acetyl-β-D-mannopyranosyl)benzene 
• 891785-95-8 (6-O-tert-butyldimethylsilyl-2,3-dideoxy-β-D-erythro-hex-2-enopyranosyl)benzene 

Relevant articles and documents

Synthesis and Mesogenic Properties of Enantiopure Trioxadecalin Derivatives Bearing a n-Alkylphenyl Substituent

Reaction of pseudo-glucal 1 with Grignard reagents derived from various 4-n-alkyl-4-bromobenzene in the presence of a catalytic amount of NiCl2(dppe), gives the corresponding unsaturated β-C-aryl glycosides 2. Desilylation and hydrogenation of these compo

Stereochemistry in palladium- and nickel-catalyzed addition of phenylmagnesium bromide to unsaturated carbohydrates

Palladium complex PdCl2(dppf) and nickel complex NiCl2(dppe) catalyze cross-coupling of unsaturated aryloxy carbohydrates with phenylmagnesium bromide. The nickel catalyst leads to inversion of configuration at the anomeric center wh