201533-32-6Relevant academic research and scientific papers
Stereoselective synthesis of α-C-glycopyranosyl isoprenoid compounds
Jégou, Anne,Pacheco, Carole,Veyrières, Alain
, p. 81 - 83 (2007/10/03)
Addition of the allylsilane Me3SiCH2C:CH2CH2CO2Me (3) to D-gluco and D-galactopyranosyl derivatives gives in good yields 3-(α-C-glycopyranosylmethyl)-but-3-enoates which can undergo oxidation to β-ketoesters, electrophile-promoted cyclizations or double bond migration.
Stereoselective synthesis of α-C-D-gluco- and D-galactopyranosyl glycosides from an isoprenoid synthon
Jegou, Anne,Pacheco, Carole,Veyrieres, Alain
, p. 14779 - 14790 (2007/10/03)
Addition of the allylsilane Me3SiCH2C:CH2CH2CO2Me to D-gluco and D- galactopyranosyl derivatives gives in good yields α-C-glycopyranosides which are easily converted into glycosylated β-keto esters, butenolide and dihydropyrone.
