201556-02-7Relevant academic research and scientific papers
Selective H2O2 oxidation of organic sulfides to sulfoxides catalyzed by cobalt(III)-salen ion
Mary Imelda Jayaseeli,Ramdass, Arumugam,Rajagopal, Seenivasan
, p. 59 - 66 (2015)
Abstract The catalytic activity of cobalt(III)-salen ion catalyzed selective H2O2 oxidation of organic sulfides to sulfoxides is examined using spectrophotometric technique. The catalytic reaction proceeds through Michaelis-Menten kinetics and the rate of the reaction is highly sensitive to the nature of the substituent present in the substrate as well as in the salen ligand. The product analyses show that the aryl methyl sulfides are selectively oxidized to the corresponding sulfoxides. Based on the spectral and kinetic studies two possible mechanisms have been proposed.
Cobalt-Catalyzed Intermolecular Hydroamination of Unactivated Alkenes Using NFSI as Nitrogen Source
Li, Linshan,Li, Yuxin,Li, Zhengming,Sun, Peng-Wei,Wang, Xinyao,Zhang, Ze
, (2022/02/23)
Cheap metal (Fe, Mn, and Co)-catalyzed hydroamination of alkenes has been an attractive method for synthesis of amines because of biocompatibility of metal, excellent Markovnikov selectivity and chemoselectivity. However, most reports are limited to unsaturated nitrogen sources (nitric oxide, azos, azides, cyano, etc.), for which aminated products are very limited. Notably, while used widely for fluorinating reaction, N-fluorobenzenesulfonimide (NFSI) as amine source for hydroamination has seldom been reported. Here we developed a cobalt-catalyzed intermolecular hydroamination of unactivated alkenes using NFSI as nitrogen source under mild conditions. The reaction exhibits excellent chemo- and regio-selectivity with no hydrofluorination or linear-selectivity products. Notably, the reaction proceeded with excellent yield even though the amount of Co(salen) catalyst was reduced to 0.2 mol%. Recently, a similar work was also reported by Zhang and coworkers (ref. 19).
Switchable Polymerization Triggered by Fast and Quantitative Insertion of Carbon Monoxide into Cobalt–Oxygen Bonds
Poli, Rinaldo,Wang, Yong,Xie, Xiaolin,Xu, Jing,Zhao, Yajun,Zhou, Xingping,Zhu, Shuaishuai
supporting information, p. 5988 - 5994 (2020/02/25)
A strategy that uses carbon monoxide (CO) as a molecular trigger to switch the polymerization mechanism of a cobalt Salen complex [salen=(R,R)-N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexanediamine] from ring-opening copolymerization (ROCOP) of ep
Oxygen-Triggered Switchable Polymerization for the One-Pot Synthesis of CO2-Based Block Copolymers from Monomer Mixtures
Zhao, Yajun,Wang, Yong,Zhou, Xingping,Xue, Zhigang,Wang, Xianhong,Xie, Xiaolin,Poli, Rinaldo
supporting information, p. 14311 - 14318 (2019/08/30)
Switchable polymerization provides the opportunity to regulate polymer sequence and structure in a one-pot process from mixtures of monomers. Herein we report the use of O2 as an external stimulus to switch the polymerization mechanism from the
Tuning ligand electronics and peripheral substitution on cobalt salen complexes: Structure and polymerisation activity
Chiang, Linus,Allan, Laura E. N.,Alcantara, Juan,Wang, Michael C. P.,Storr, Tim,Shaver, Michael P.
, p. 4295 - 4304 (2014/03/21)
A series of cobalt salen complexes, where salen represents an N 2O2 bis-Schiff-base bis-phenolate framework, are prepared, characterised and investigated for reversible-termination organometallic mediated radical polymerisation (RT-OMRP). The salen ligands contain a cyclohexane diimine bridge and systematically altered para-substituted phenoxide moieties as a method to examine the electronic impact of the ligand on complex structure and reactivity. The complexes are characterised by single crystal X-ray diffraction, cyclic voltammetry, X-ray photoelectron spectroscopy, electron paramagnetic resonance spectroscopy and computational methods. Structural studies all support a tailorable metal centre reactivity altered by the electron-donating ability of the salen ligand. RT-OMRP of styrene, methyl methacrylate and vinyl acetate is reported and suggests that cobalt-carbon bond strength varies with the ligand substitution. Competing β-hydrogen abstraction affords long-chain olefin-terminated polymer chains and well controlled vinyl acetate polymerisations, contrasting with the lower temperature associative exchange mechanism of degenerative transfer OMRP.
Catalytic activity of salenCo(III)OAc complex in the reaction of addition of carboxylic acids to terminal epoxides
Bukowska, Agnieszka,Bukowski, Wiktor,Noworól, Jaros?aw
, p. 7 - 10 (2008/10/09)
The catalytic activity and regioselectivity were studied of the salenCo(III)OAc complex in the reaction of addition of aliphatic carboxylic acids to a series of terminal epoxides (epichlorohydrin, 1,2-epoxybutane, propylene oxide, tert-butyl glycidyl ether and 2,3-epoxypropyl phenyl ether). The reduction in the activity in the order: acetic > acrylic > methacrylic acid was found. The regioselectivity of the addition was independent on carboxylic acid nature and depended on the nature of the epoxide. The best regioselectivity for the addition to epichlorohydrin was observed. The catalytic activity and regioselectivity of salenCo(III)OAc were compared with those for chromium(III) acetate catalyst. The catalytic activity and regioselectivity were studied of the salenCo(III)OAc complex in the reaction of addition of aliphatic carboxylic acids (2) to a series of terminal epoxides (3). The reduction in the activity in the order: acetic > acrylic > methacrylic acid was found. The regioselectivity of the addition was independent on carboxylic acid nature and depended on the nature of the epoxide.
