20157-03-3Relevant academic research and scientific papers
Triazole acetyl gold(III) catalyzed Meyer-Schuster rearrangement of propargyl alcohols
Yang, Yongchun,Shen, Yanan,Wang, Xiaoli,Zhang, Yao,Wang, Dawei,Shi, Xiaodong
, p. 2280 - 2282 (2016)
A new type triazole acetyl gold(III) was prepared and found to be an effective catalyst in Meyer-Schuster rearrangement of propargyl alcohols. The reactions proceeded well under much milder conditions to afford enones bearing a wide range of functional groups, thereby opening a new avenue for gold(III) catalysis. In addition, TriaAuCl2 catalyst was also effective on promotion of a-haloenones synthesis.
