201738-82-1Relevant academic research and scientific papers
Catalytic enantioselective amination of silyl enol ethers using chiral dirhodium(II) carboxylates: Asymmetric formal synthesis of (-)-metazocine
Anada, Masahiro,Tanaka, Masahiko,Washio, Takuya,Yamawaki, Minoru,Abe, Takumi,Hashimoto, Shunichi
, p. 4559 - 4562 (2008/03/13)
(Chemical Equation Presented) Dirhodium(II) tetrakis[N- tetrafluorophthaloyl-(S)-tert-leucinate], Rh2(S-TFPTTL)4, is an exceptionally efficient catalyst for enantioselective aminations of silyl enol ethers derived from acyclic ketone
REGIOSPECIFIC ORTHO OXYFUNCTIONALIZATION OF SUBSTITUTED BENZENES WITH SINGLET OXYGEN
Saito, Isao,Nagata, Ryu,Kotsuki, Hiyoshizo,Matsuura, Teruo
, p. 1717 - 1720 (2007/10/02)
A new procedure for regiospecific ortho oxyfunctionalization of phenylacetones, phenylacetic acid esters and phenylacetaldehyde has been developed.The method involves tert-butyldimethylsilylation, singlet oxygenation and successive reduction.
