201747-53-7Relevant academic research and scientific papers
Electrolytic Partial Fluorination of Organic Compounds. 24.1 Highly Regioselective Anodic Monofluorination of 2-Benzothiazolyl and 5-Chloro-2-benzothiazolyl Sulfides
Hou, Yankun,Higashiya, Seiichiro,Fuchigami, Toshio
, p. 9173 - 9176 (1997)
Electrochemical fluorination of 2-benzothiazolyl and 5-chloro-2-benzothiazolyl sulfides was successfully carried out using Et4NF·3HF as a supporting electrolyte and fluoride ion source in dimethoxyethane to provide the corresponding α-monofluorinated sulfides in good yields. Fluorination took place selectively at the position α to the sulfur atom of the sulfides, and the heterocyclic moieties were not fluorinated at all.
Fluoro-Julia olefination as a mild, high-yielding route to α-fluoro acrylonitriles
Del Solar, Maria,Ghosh, Arun K.,Zajc, Barbara
supporting information; experimental part, p. 8206 - 8211 (2009/04/11)
(Chemical Equation Presented) Synthesis of a novel, stable reagent (1,3-benzothiazol-2-ylsulfonyl)fluoroacetonitrile from readily synthesized ethyl α-(1,3-benzothiazol-2-ylsulfanyl)-α-fluoroacetate is reported. Aldehydes undergo condensations with (1,3-be
