201791-69-7Relevant academic research and scientific papers
One- And Two-Electron Reactions from the Rearrangement of α-Ketocyclopropanes by O-Stannyl Ketyls
Enholm, Eric J.,Jia, Zhaozhong J.
, p. 9159 - 9164 (1997)
This work summarizes an investigation of the bifunctional reactions of tin(IV) enolates and radicals derived from the cleavage rearrangement of ketocyclopropanes with tributyltin hydride. The intermediates provide an unparalleled dual reactivity in synthe
From selective transfer hydrogenation to selective hydrogen auto-transfer process: An efficient method for the synthesis of alkenyl ketones via iridium-catalyzed α-alkylation of ketones with alkenyl alcohols
Li, Feng,Li, Shun,Meng, Chong,Xu, Xiangchao,Yang, Chenchen,Yang, Jiazhi,Yu, Junjie
, p. 335 - 343 (2021/10/07)
A strategy for the synthesis of alkenyl ketones via the α-alkylation of ketones with alkenyl ketones has proposed and accomplished. In the presence of a metal–ligand bifunctional catalyst [Cp*Ir(2,2′-bpyO)(H2O)], a series of desirable products
