201946-07-8Relevant academic research and scientific papers
Synthesis of fused systems containing an angular nitrogen atom from substituted 2-benzyl-4-hydrazinopyridimines
Danagulyan,Sahakyan,Panosyan
, p. 185 - 189 (2000)
The condensation of substituted 2-benzyl-4-hydrazinopyrimidines with phenylpyruvic acid gave the corresponding hydrazones, which cyclize upon the action of POCI3 to give derivatives of pyrimido[6,1-c][1,2,4]-triazine. The substituted 2-benzylpyrimidinylhydrazides of some carboxylic acids react with POCI3 to give 1,2,4-triazolo[4,3-c]pyrimidines. The reaction of 7-benzyl-5-methyl-1-phenyl-1,2,4-triazolo[23-c]pyrimidine with sodium ethylate leads to rearrangement and formation of 7-benzyl-5-methyl-2-phenyl-1,2,4-triazolo[2,3-c]pyrimidine.
