202120-83-0

Basic information

• Product Name: Cyclopentanone, 3-(1,3-dioxolan-2-yl)-
• Synonyms: Cyclopentanone, 3-(1,3-dioxolan-2-yl)-
• CAS NO: 202120-83-0
• Molecular Formula: C8H12O3
• Molecular Weight: 156.18
• Mol File: 202120-83-0.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Cyclopentanone, 3-(1,3-dioxolan-2-yl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclopentanone, 3-(1,3-dioxolan-2-yl)-(202120-83-0)
• EPA Substance Registry System: Cyclopentanone, 3-(1,3-dioxolan-2-yl)-(202120-83-0)

Safety Data

• Hazardous Substances Data: 202120-83-0(Hazardous Substances Data)

Upstream product

• 151951-76-7 (S)-2-[(2,4,6-triisopropylphenyl)sulfinyl]-2-cyclopentenone 
• 220077-00-9 (2R,3R,R_S)-3-(1,3-dioxolan-2-yl)-2-[(2,4,6-triisopropylphenyl)sulfinyl]-1-cyclopentanone 
• 220076-99-3 (2R,3R,R_S)-3-(1,3-dioxolan-2-yl)-2-[(2,4,6-trimethylphenyl)sulfinyl]-1-cyclopentanone 

Relevant articles and documents

Photo-induced intermolecular radical β-addition to chiral α- (arylsulfinyl) enones

The reactions of α-(arylsulfinyl) enones with alkyl radicals having a hydroxy or acetal group were examined under photo-irradiation in the presence of benzophenone. High diastereoselectivity was observed in the photo-induced radical reaction of 2-(arylsulfinyl)-2-cyclopentenones having a bulky aryl group, such as the 2,4,6-triisopropylphenyl or 2,4, 6-trimethylphenyl group. The photo-induced reaction of 3-[(2,4,6-triisopropylphenyl)sulfinyl]-3- pentene-2-one in 1,3-dioxolane also gave a single diastereomer of the 1,3- dioxolan-2-yl adduct.