20224-39-9Relevant academic research and scientific papers
One-pot rhodium(I)-catalyzed hydroboration of alkenes: Radical conjugate addition
Renaud, Philippe,Ollivier, Cyril,Weber, Valery
, p. 5769 - 5772 (2003)
B-Alkylcatecholboranes, prepared by rhodium-(I)-catalyzed hydroboration of alkenes, are suitable radical precursors for conjugate addition to activated olefins. This procedure proved to be particularly useful for the control of the regio- and chemoselectivity of such tandem processes. Enantioselective hydroboration has also been successfully coupled with radical chain reaction in a one-pot process.
The Oxidation of Norbornadiene and Some Derivatives using Pseudomonas sp.
Geary, Philip J.,Pryce, Robert J.,Roberts, Stanley M.,Ryback, George,Winders, John A.
, p. 204 - 205 (2007/10/02)
Norbornadiene is oxidized by a Pseudomonad to give the diol (2) (35percent) while 7-phenylnorbornadiene furnishes 3-norbornadienylcyclohexa-3,5-diene-1,2-diol (10) (41percent) on incubation with the same organism; cyclization reactions involving the acetonide (15) have been investigated.
