202276-33-3Relevant articles and documents
Photoreactions with a Twist: Atropisomerism-Driven Divergent Reactivity of Enones with UV and Visible Light
Vallavoju, Nandini,Sreenithya, Avadakkam,Ayitou, Anoklase J.-L.,Jockusch, Steffen,Sunoj, Raghavan B.,Sivaguru, Jayaraman
, p. 11339 - 11348 (2016)
Light-induced transformation of atropisomeric and achiral enones displays divergent reactivity. Photocyclization leading to 3,4-dihydroquinolin-2-one was observed with achiral enone carboxamide, whereas the atropisomeric enone carboxamides underwent hydro
Cu-Catalyzed Intramolecular Amidation of Unactivated C(sp3)-H Bonds to Synthesize N-Substituted Indolines
Pan, Fei,Wu, Bin,Shi, Zhang-Jie
supporting information, p. 6487 - 6490 (2016/05/02)
A copper-catalyzed intramolecular amidation of unactivated C(sp3)-H bonds to construct indoline derivatives has been developed. Such an amidation proceeded well at primary C-H bonds preferred to secondary C-H bonds. The transformation owned a b
Rotational features of carbon-nitrogen bonds in axially chiral o-tert- butyl anilides and related molecules. Potential substrates for the 'prochiral auxiliary' approach to asymmetric synthesis
Curran, Dennis P.,Hale, Gregory R.,Geib, Steven J.,Balog, Aaron,Cass, Quezia B.,Degani, Ana Luiza G.,Hernandes, Marcelo Z.,Freitas, Luiz Carlos G.
, p. 3955 - 3975 (2007/10/03)
A new strategy for asymmetric induction termed the 'prochiral auxiliary' approach is introduced. Reactions of acylating agents with prochiral N- methyl-o-tert-butyl aniline provide anilides that are axially chiral by virtue of restricted rotation about th
