20231-45-2

Basic information

• Product Name: pi-oxocamphor
• Synonyms: pi-oxocamphor
• CAS NO: 20231-45-2
• Molecular Formula: C10H14O2
• Molecular Weight: 166.21696
• Mol File: 20231-45-2.mol
• Article Data: 1

Chemical Properties

• Boiling Point: 234.44°C (rough estimate)
• Flash Point: 89.6°C
• Appearance: /
• Density: 0.9817 (rough estimate)
• Vapor Pressure: 0.0305mmHg at 25°C
• Refractive Index: 1.4859 (estimate)
• CAS DataBase Reference: pi-oxocamphor(CAS DataBase Reference)
• NIST Chemistry Reference: pi-oxocamphor(20231-45-2)
• EPA Substance Registry System: pi-oxocamphor(20231-45-2)

Safety Data

• Hazardous Substances Data: 20231-45-2(Hazardous Substances Data)

Usage

InChI:InChI=1/C10H14O2/c1-9-4-3-7(5-8(9)12)10(9,2)6-11/h6-7H,3-5H2,1-2H3

Relevant articles and documents

Synthesis, structure and chiroptical spectra of the bicyclic α-diketones, imides and dithioimides related to santenone

Isomeric α-diketones, imides and dithioimides related to santenone were prepared in a multistep synthesis from (+)-camphor and their CD spectra compared with those of analogous chromophoric systems related to camphor. In the case of conformationally rigid α-diketones the methyl substituents at C-7, lying on the symmetry plane of the chromophore, exert only a weak contribution to the n-π* Cotton effects. In contrast, the Cotton effect magnitudes of the anhydrides, imides and dithioimides are significantly affected by the substituents at C-8. The steric interaction of these chromophores with the syn-methyl group at C-8, leading to the chromophore distortion, was confirmed by X-ray crystallographic studies. Copyright (C) 2000 Elsevier Science Ltd.