202803-14-3

Upstream product

• 51450-27-2 3,7-anhydro-1,2-dideoxy-D-glycero-D-gulo-oct-1-enitol 
• 98-59-9 p-toluenesulfonyl chloride 
• 572-09-8 2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide 
• 51450-26-1 4,5,6,8-Tetra-O-acetyl-3,7-anhydro-1,2-didesoxy-β-D-gluco-oct-1-enitol 

Downstream Products

• 261956-04-1 3,7-anhydro-4,5,6-tri-O-benzyl-1,2,8-trideoxy-D-gulo-oct-1,7-dienitol 
• 202803-16-5 3,7-anhydro-4,5,6-tri-O-benzoyl-1,2,8-trideoxy-D-gulo-oct-1,7-dienitol 
• 854654-14-1 3,7-anhydro-4,5,6-tri-O-benzyl-8-bromo-1,2,8-trideoxy-D-glycero-D-gulo-oct-1-enitol 
• 916670-00-3 4,5,6-tri-O-acetyl-3,7-anhydro-1,2-dideoxy-8-O-(4-tolylsulfonyl)-D-glycero-D-gulo-oct-1-enitol 
• 202803-15-4 3,7-anhydro-4,5,6-tri-O-benzoyl-1,2-dideoxy-8-O-(4-tolylsulfonyl)-D-glycero-D-gulo-oct-1-enitol 

Relevant academic research and scientific papers

Claisen rearrangement of carbohydrate-derived precursors towards highly functionalized cyclooctenones with L-xylo, D-arabino and L-lyxo configuration and their diastereoselective transformations

D-Glucose and D-mannose have been transformed into precursors incorporating allyl vinyl ether substructures. Both thermally and catalytically, these cyclic allyl vinyl ethers could be converted into the corresponding Claisen rearrangement products. The co

Alternative approaches towards glycosylated eight-membered ring compounds employing Claisen rearrangement of mono and disaccharide allyl vinyl ether precursors

Highly functionalized eight-membered rings having a glycosidic residue were synthesized in two different ways involving either glycosylation of a sugar-derived cyclooctenone with high stereocontrol as well as a Claisen rearrangement of a disaccharide deri

From D-Glucose to a New Chiral Cyclooctenone

Keywords: carbocycles; carbohydrates; rearrangements