202866-11-3Relevant academic research and scientific papers
Stereoselective formation of (Z)-γ-substituted allylsilanes by the titanocene(II)-promoted reaction of thioacetals with trialkyl(allyl)silanes
Fujiwara, Tooru,Takamori, Mayumi,Takeda, Takeshi
, p. 51 - 52 (1998)
The reaction of organotitanium species prepared by the desulfurizative titanation of thioacetals with (C5H5)2Ti-[P(OEt)3]2 in the presence of trialkyl(allyl)silanes gives γ-substituted allylsilanes with Z stereoselectivity.
Silicon-directed Bamford-Stevens Reaction of β-Trimethylsilyl N-Aziridinylimines
Sarkar, Tarun K.,Ghorai, Binay K.
, p. 1184 - 1185 (2007/10/02)
The Me3Si group in β-trimethylsilyl N-aziridinylimines is able to direct the Bamford-Stevens reaction with or without rhodium acetate as catalyst to give allylic silanes as major or exclusive products.
