202928-34-5

Basic information

• Product Name: 2-BroMo-2'-diphenylphosphinobiphenyl
• Synonyms: 2-BroMo-2'-diphenylphosphinobiphenyl
• CAS NO: 202928-34-5
• Molecular Formula: C₂₄H₁₈BrP
• Molecular Weight: 417.277481
• Mol File: 202928-34-5.mol
• Article Data: 3

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-BroMo-2'-diphenylphosphinobiphenyl(CAS DataBase Reference)
• NIST Chemistry Reference: 2-BroMo-2'-diphenylphosphinobiphenyl(202928-34-5)
• EPA Substance Registry System: 2-BroMo-2'-diphenylphosphinobiphenyl(202928-34-5)

Safety Data

• Hazardous Substances Data: 202928-34-5(Hazardous Substances Data)

Upstream product

• 1806-29-7 2,2'-dihydroxybiphenyl 
• 583-55-1 1-Bromo-2-iodobenzene 
• 244205-40-1 (2-bromophenyl)boronic acid 
• 13029-09-9 2,2'-dibromobiphenyl 
• 1079-66-9 chloro-diphenylphosphine 

Downstream Products

• 1088-00-2 9-phenyl-9-phosphafluorene 
• 1031-13-6 5-phenyl-5H-dibenzophosphole-5-oxide 
• 1601393-02-5 C₂₆H₂₀BrO₃P 
• 1377584-17-2 C₄₄H₄₂NOP 
• 1377584-16-1 C₃₆H₂₆NOP 
• 928622-89-3 2-bromo-2'-(diphenylphosphine oxide)biphenyl 

Relevant articles and documents

Palladium-catalyzed R2(O)P directed C(sp2)-H acetoxylation

A novel and efficient Pd-catalyzed C-H acetoxylation is described. The approach uses R2(O)P as a directing group to synthesize various substituted 2′-phosphorylbiphenyl-2-OAc compounds. Notably, the reaction exhibits smooth operation under mild conditions and shows good functional group tolerance. Products are obtained with high selectivity and yields. This journal is the Partner Organisations 2014.

Enantioselective catalysis 113: New menthylphosphane ligands differing in steric and electronic properties

A concept for bisphosphane ligands was developed, in which chirality is derived from the optically active (1R,3R,4S)-menthyl substituents in PMen2 groups and the backbone between the phosphorus units is varied (o-phenylene, 2,2'-biphenylene, 1,1'-ferrocenediyl); one of the two PMen2 groups was also replaced by a PPh2 unit. The synthesis and characterisation of seven new menthylphosphanes is described. Emphasis is put on the NMR assignment of the menthyl protons by two-dimensional methods and 13C-1H shift correlation. The ligands have been used in Rh and Ni complexes in several model reactions of enantiosclective catalysis giving optical inductions in the low to middle range.