2030-37-7Relevant academic research and scientific papers
Alkyltransferase Model Reactions: Synthesis of Sulfonium and Ammonium Compounds Containing Neighboring Nucleophiles. Kinetic Studies of the Intramolecular Reaction of Amino, Hydroxy, Phenoxy, and Mercapto Onium Salts
Miller, Robert J.,Kuliopulos, Athan,Coward, James K.
, p. 3436 - 3448 (2007/10/02)
The synthesis of a series of sulfonium and ammonium salts containing a variety of neighboring nucleophiles is described.Several of these molecules undergo facile cyclization reactions with rate enhancements of ca. 1E5 over the corresponding intermolecular
