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203060-14-4

trans-[Rh(OD)(C=CDPh)(PiPr3)2] is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 203060-14-4 Structure

  • Basic information

    1. Product Name: trans-[Rh(OD)(C=CDPh)(PiPr3)2]
    2. Synonyms:
    3. CAS NO:203060-14-4
    4. Molecular Formula:
    5. Molecular Weight: 544.512
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 203060-14-4.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: trans-[Rh(OD)(C=CDPh)(PiPr3)2](CAS DataBase Reference)
    10. NIST Chemistry Reference: trans-[Rh(OD)(C=CDPh)(PiPr3)2](203060-14-4)
    11. EPA Substance Registry System: trans-[Rh(OD)(C=CDPh)(PiPr3)2](203060-14-4)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 203060-14-4(Hazardous Substances Data)

203060-14-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 203060-14-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,0,3,0,6 and 0 respectively; the second part has 2 digits, 1 and 4 respectively.
Calculate Digit Verification of CAS Registry Number 203060-14:
(8*2)+(7*0)+(6*3)+(5*0)+(4*6)+(3*0)+(2*1)+(1*4)=64
64 % 10 = 4
So 203060-14-4 is a valid CAS Registry Number.

203060-14-4Upstream product

203060-14-4Downstream Products

203060-14-4Relevant articles and documents

Dinuclear rhodium complexes containing a linear C2RhC4RhC2 chain

Gil-Rubio, Juan,Laubender, Matthias,Werner, Helmut

, p. 1202 - 1207 (2008/10/08)

The reaction of trans-[RhCl(=C=CHPh)(PiPr3)2] (1) and trans-[RhCl(=C=CMe2)(PiPr3)2] (3) with 50% aqueous NaOH, in the presence of TEBA, afforded the hydroxorhodium complexes trans-[Rh(OH)(=C=CRR′)(PiPr3)2] (2, 4) in good to excellent yield. Compound 2 (R = H, R′ = Ph) reacted with D2O to give trans-[Rh(OD)(=C=CHPh)(PiPr3)2] (2-d) and with Br?nsted acids HX (X = CF3CO2, OPh, C≡CPh) to yield the corresponding derivatives trans-[Rh(X)(=C=CHPh)(PiPr3)2] (5-7), respectively. Treatment of 2 and 4 with Ph3-SnC≡CC≡CSnPh3 also led to the displacement of the hydroxo ligand and to the formation of the dinuclear complexes tran,trans-[{Rh(=C=CRR′)(PiPr3)2} 2(μ-C4)] (8, 9) in 75-80% yield. The X-ray crystal structure analysis of 9 revealed the presence of a linear 10-atom C=C=RhC≡CC≡CRh=C=C chain with the midpoint of the central C-C bond as a crystallographic center of symmetry.

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