203131-19-5

Basic information

• Product Name: Silane, tris(1-methylethyl)[(4-methyl-2-furanyl)oxy]-
• CAS NO: 203131-19-5
• Molecular Formula: C14H26O2Si
• Molecular Weight: 254.445
• Mol File: 203131-19-5.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: Silane, tris(1-methylethyl)[(4-methyl-2-furanyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Silane, tris(1-methylethyl)[(4-methyl-2-furanyl)oxy]-(203131-19-5)
• EPA Substance Registry System: Silane, tris(1-methylethyl)[(4-methyl-2-furanyl)oxy]-(203131-19-5)

Safety Data

• Hazardous Substances Data: 203131-19-5(Hazardous Substances Data)

Upstream product

• 616-02-4 citraconic acid anhydride 
• 80522-42-5 triisopropylsilyl trifluoromethanesulfonate 
• 6124-79-4 4-methyl-2(5H)-furanone 

Downstream Products

• 21053-63-4 methyl-3 phenyl-4 Δ²⁽³⁾-butyrolactone 
• 40834-42-2 5-hydroxy-4-methyl-5H-furan-2-one 
• 39007-93-7 sesquirosefuran 

Relevant articles and documents

Biomimetic total synthesis of litseaverticillols B, E, I, and J and structural reassignment of litseaverticillol E

Equation presented. The first total synthesis of litseaverticillols B (1), E (2), I (4), and J (5) as well as the structural reassignment of litseaverticillol E (2) have been achieved by means of a biomimetic sequence of transformations during which a [4 + 2]-initiated reaction cascade and an ene reaction, both involving singlet oxygen (1O2), formed key steps. The reassignment of the structure of litseaverticillol E (3) to include an allylic hydroperoxide provides strong support for our biogenetic hypothesis.

Illustrating the power of singlet oxygen chemistry in a synthetic context: Biomimetic syntheses of litseaverticillols A-G, I and J and the structural reassignment of litseaverticillol E

Biomimetic syntheses of the litseaverticillols A-G, I and J are reported herein. The syntheses rely heavily on the application of two different modes of reaction for photochemically generated singlet oxygen, namely, the [4+2] cycloaddition of singlet oxygen (1O2) with furans and the ene reaction of 1O2 with double bonds. The highlight of these syntheses is a one-pot cascade sequence, involving five synthetic operations initiated by a [4+2] reaction, to form the fully functionalised litseaverticillol core. A series of regioselective ene reactions are then used to appositely functionalise the side chains. The synthesis of litseaverticillol E (both its originally proposed and its actual structures) allows a structural reassignment of this natural product.

Synthesis of Penta-2,4-dien-1-imines and 1,2-Dihydropyridines by Rhodium-Catalyzed Reaction of N-Sulfonyl-1,2,3-triazoles with 2-(Siloxy)furans

A rhodium(II)-catalyzed reaction of N-sulfonyl-1,2,3-triazoles with 2-(siloxy)furans is reported. Either open-chain penta-2,4-dien-1-imines or cyclic 1,2-dihydropyridines are selectively obtained depending on the ligand on rhodium(II).