203177-96-2Relevant academic research and scientific papers
Nucleoside analog-based phosphonates via photochemical, single electron transfer (SET) induced rearrangements of allyl phosphites
Jeon, Geun Sook,Bentrude, Wesley G.
, p. 927 - 930 (2007/10/03)
The photochemical SET rearrangement of nucleoside analog-based phosphites 12 and 13, initiated by the singlet excited state of DCN, affords the corresponding diethyl phosphonates 14 and 15. Deprotection of 15 gives phosphonate 16. Treatment of 14 - 16 with base yields the vinylphosphonates 17-19 as the (E)- and (Z)-diastereomers.
