203248-32-2

Upstream product

• 16212-05-8 (allylsulfonyl)benzene 
• 203248-30-0 (2R,3R,4R)-2,3-epoxy-4-(methoxymethyl)oxy-1-{[(4'-methoxyphenyl)methyl]oxy}hexyl-6-methanesulfonate 
• 313218-74-5 tert-Butyl-((R)-3-methoxymethoxy-4-trityloxy-butoxy)-dimethyl-silane 
• 313218-72-3 (R)-3-Methoxymethoxy-4-trityloxy-butyric acid methyl ester 
• 313218-73-4 (R)-3-Methoxymethoxy-4-trityloxy-butan-1-ol 
• 203248-28-6 (2R,3R,4R)-6-(tert-butyldimethylsilyl)oxy-2,3-epoxy-4-(methoxymethyl)oxy-1-{[(4'-methoxyphenyl)methyl]oxy}hexane 
• 313218-76-7 (R)-3-[(2R,3R)-3-(4-Methoxy-benzyloxymethyl)-oxiranyl]-3-methoxymethoxy-propan-1-ol 
• 203248-26-4 (E)-(R)-6-(tert-butyldimethylsilyl)oxy-4-(methoxymethyl)oxy-2-hexen-1-ol 
• 203248-24-2 (R)-4-(tert-butyldimethylsilyl)oxy-2-(methoxymethyl)oxybutan-1-ol 
• 203248-39-9 (E)-(R)-6-(tert-Butyl-dimethyl-silanyloxy)-4-methoxymethoxy-hex-2-enoic acid ethyl ester 

Downstream Products

• 313218-77-8 (3S,3aS,4R,6aR)-6a-Benzenesulfonyl-3-(4-methoxy-benzyloxymethyl)-4-methoxymethoxy-hexahydro-cyclopenta[c]furan-1-ol 
• 203248-34-4 (1S,4S,5S,6R)-6-(methoxymethyl)oxy-4-{[(4'-methoxyphenyl)methoxy]oxy}methyl-3-oxabicyclo[3.3.0]octan-2-one 
• 313218-78-9 (3S,3aS,4R,6aR)-6a-Benzenesulfonyl-3-(4-methoxy-benzyloxymethyl)-4-methoxymethoxy-hexahydro-cyclopenta[c]furan-1-one 
• 313218-67-6 (1S,2S,4S,5S,6R)-2-methoxy-6-(methoxymethyl)oxy-4-{[(4'-methoxyphenyl)methoxy]oxy}methyl-3-oxabicyclo[3.3.0]octane 

Relevant academic research and scientific papers

Total synthesis of marine oxylipin bacillariolides I-III

Marine oxylipin bacillariolides I-III were synthesized from (R)-malic acid, using diastereoselective one-pot formation of the chiral cyclopentane derivative from the anion of allyl phenyl sulfone and chiral epoxymesylate as the key reaction. (C) 2000 Elsevier Science Ltd.

Synthesis of cyclopentane-containing marine eicosanoid bacillariolide II

Marine eicosanoid bacillariolide II was synthesized from (R)-malic acid, involving the diastereoselective one-pot formation of chiral cyclopentane derivative 12 from the anion of allyl phenyl sulfone and chiral epoxymesylate 11 as the key step.