203393-61-7Relevant academic research and scientific papers
Stereoselective synthesis of (Z)-α-organothiovinyltosylates and their application in the synthesis of highly functionalized vinylic sulfides
Braga,Emmerich,Silveira,Martins,Rodrigues
, p. 371 - 373 (2001)
Thioacetylenes 1 afford, upon treatment with p-toluenesulfonic acid in dichloromethane, (O,S)-ketene acetals 2 which can act as useful α-(organothio)vinyl carbocation equivalents, opening a novel route to functionalized vinylic sulfides.
