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(CH3C6H4CH(CH3)2)2Ru2(SC6H5)3(1+)*OSO2CF3(1-)=[(CH3C6H4CH(CH3)2)2Ru2(SC6H5)3]OSO2CF3 is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

203459-45-4

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203459-45-4 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 203459-45-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,0,3,4,5 and 9 respectively; the second part has 2 digits, 4 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 203459-45:
(8*2)+(7*0)+(6*3)+(5*4)+(4*5)+(3*9)+(2*4)+(1*5)=114
114 % 10 = 4
So 203459-45-4 is a valid CAS Registry Number.

203459-45-4Downstream Products

203459-45-4Relevant academic research and scientific papers

Mononuclear indoline complexes. 2. Synthesis, structure, and reactivity of [(cymene)Ru(η1-N-indoline)(CH3CN) 2](OTf)2

Vasquez, Lisa D.,Noll,DuBois, M. Rakowski

, p. 976 - 981 (1998)

The complex [(cymene)Ru(η1-indoline)(CH3CN)2](OTf) 2, 1, has been synthesized by the reaction of [(cymene)Ru(OTf)2]x with indoline in acid solution and characterized by an X-ray diffraction study. Bond distances for the indoline ligand are compared to those reported recently for other η1- and η6-indoline complexes. Complex 1 rearranged to [(cymene)Ru(η6-indoline)](OTf)2 when heated in dichloromethane solution. The titration of an aqueous solution of 1 has been carried out, and the pKa of the coordinated ligand was determined to be 5.2. The value is similar to that reported for the indolinium ion. Ligand-exchange reactions of 1 have been studied. Deprotonation of the η1-indoline ligand in 1 results in dehydrogenation of the ligand to form free indole and ruthenium hydride products. The deprotonation of 1 in the presence of an alkene has been found to result in a hydrogen-transfer reaction to form alkane. Characteristics of the hydrogen-transfer reactions are discussed.

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