20351-26-2Relevant academic research and scientific papers
Process for preparation of a benzofuran derivative
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Page/Page column 13, (2010/01/31)
An industrially useful process for producing benzofuran derivatives of formula (1) by formylating a compound of formula (2) (where A1 is a protective group), followed by reaction with a compound of formula (4) (where X1 is a halogen atom), then performing a cyclizing reaction and subsequently performing a reaction for hydroxyl group deprotection.
REGIOSPECIFIC AND STEREOSPECIFIC SUBSTITUTION OF HYDROXYL IN ALIPHATIC ALCOHOLS BY HALOGEN
Matveeva, E. D.,Kurts, A. L.,Yalovskaya, A. I.,Nikishova, N. G.,Bundel', Yu. G.
, p. 642 - 646 (2007/10/02)
A new system containing triphenylphosphine and trichloro- and tribromoacetic ester makes it possible to substitute the hydroxyl group in alcohols by halogen.Regiospecific and stereospecific substitution of the hydroxyl by the halogen takes place as a result of the reaction of primary and secondary aliphatic alcohols and of 2-alkenols, susceptible to isomerization processes, with this system.
