203632-84-2

Upstream product

• 203632-81-9 (1S,3S,5S)-4-bromo-4-methyl-6-oxabicyclo[3.2.1]octan-7-one 
• 214333-54-7 2-methyl-5-phenylseleno-5-phenylthio-2-pentene 
• 203632-82-0 (1R,4S,6R)-6-bromo-1-methyl-2-oxabicyclo[2.2.2]octan-3-one 
• 214333-51-4 5,5-bis(phenylseleno)-2-methyl-2-pentene 
• 870-63-3 prenyl bromide 
• 102208-60-6 (S)-4-methyl-3-cyclohexene-1-carboxylic acid 

Downstream Products

• 214333-57-0 (2R*,3R*,1'S,3'S,4'R)-2-(3',4'-epoxy-4'-methylcyclohexyl)-6-methyl-3-phenylthio-5-hepten-2-ol 
• 214333-60-5 (2R,3R,6S,7Z)-2-acetoxy-3-methanesulfonyloxy-7,10-bisaboladiene 
• 214333-58-1 (2R,3R,6S,7Z)-2-acetoxy-3-hydroxy-7,10-bisaboladiene 
• 214333-59-2 (2S,3S,6S,7Z)-3-acetoxy-2-hydroxy-7,10-bisaboladiene 
• 203632-86-4 (1R,2R,4S)-4-((Z)-1,5-Dimethyl-hexa-1,4-dienyl)-1-methyl-cyclohexane-1,2-diol 
• 111613-41-3 (Z)-(1R,2S,4S)-4-(1',5'-Dimethylhexa-1',4'-dienyl)-1,2-epoxy-1-methylcyclohexane 

Relevant academic research and scientific papers

A convenient synthesis of (2s,3r,6s,7z)- and (2r,3s,6s,7z)-2,3-epoxy- 7,10-bisaboladiene, the sex pheromones of the southern green stink bug (nezara viridula)

(2S,3R,6S,7Z)-2,3-Epoxy-7,10-bisaboladiene, a sex pheromone component of the southern green stink bug, Nezara viridula (L.) was synthesized stereoselectively in four steps (19% overall yield) from (S)-4-methyl-3- cyclohexene-1-carboxylic acid. This epoxy bisaboladiene was converted in three more steps (64% yield) to its (2R,3S,6S,7Z)-isomer, another sex pheromone component of the southern green stink bug, by inverting the configuration of the epoxide ring.