203726-07-2Relevant academic research and scientific papers
Michael reaction of acyclic β-enaminoesters derived from α-alkyl-β-ketoesters and chiral α-methylbenzylamine: Stereoselective generation of quaternary carbon centres
Maiti,Ghoshal,Mukhopadhyay,Achari,Banerjee
, p. 1072 - 1080 (2007/10/03)
Michael reaction of electrophilic olefins with acyclic β-enaminoester substrates derived from α-substituted β-ketoesters and (R)- or (S)-α-methylbenzylamine under neutral conditions resulted in the enantioselective formation of quaternary centres. The add
A short enantioselective synthetic route to (+)-cassiol
Maiti, Soumen,Achari, Basudeb,Banerjee, Asish K.
, p. 129 - 130 (2007/10/03)
A formal total synthesis of (+)-cassiol (2) from ethyl α-methylpropionylacetate (3) was achieved through the application of asymmetric Michael reaction.
