20378-54-5Relevant academic research and scientific papers
Atom economical synthesis of: N -alkylbenzamides via the iron(III) sulfate catalyzed rearrangement of 2-alkyl-3-aryloxaziridines in water and in the presence of a surfactant
Kra?em, Jamil,Ollevier, Thierry
supporting information, p. 1263 - 1267 (2017/08/15)
A green and mild synthetic route to N-alkylbenzamides involves eco-friendly one pot synthesis of 2-alkyl-3-aryloxaziridines from N-alkylamines and benzaldehydes followed by iron(iii) sulfate catalyzed rearrangement to the corresponding amides in water as the solvent and in the presence of sodium dodecyl sulfate as the surfactant. This green approach affords N-alkylbenzamides in high overall yields under simple and minimum manipulation.
Stereospecific synthesis of 2-alkyl-3-aryloxaziridines from prochiral and chiral N-arylidenealkylamines by use of the benzonitrile-hydrogen peroxide system
Kraiem,Kacem,Khiari,Ben Hassine
, p. 263 - 271 (2007/10/03)
Benzonitrile-hydrogen peroxide oxidation of prochiral and chiral imines 1a-h leads to racemic (E)-oxaziridines (R,R/S,S) and nonracemic (E)-oxaziridines (R,R,R/S,S,R) 2a-h, respectively.
Multinuclear Magnetic Resonance Study of Oxaziridines
Cudic, Mane,Herrmann, Rudolf
, p. 461 - 467 (2007/10/02)
NMR data (13C, 15N, 17O) for the three ring atoms of various oxaziridines are compared.Their significance for the prediction of the enantioselectivity of the oxidation of sulphides by chiral oxaziridines is discussed.Key Words: Oxaziridines Multinuclear (
PHASE-TRANSFER CATALYTIC SYNTHESIS OF OXAZIRIDINES
Bulachkova, A. I.,Koldobskii, G. I.,Drozdetskii, A. G.,Tereshchenko, G. F.
, p. 632 - 636 (2007/10/02)
The phase-transfer catalytic oxidation of imines is a general method for the preparation of oxaziridines with various structures.Oxone (2KHSO5*KHSO4*K2SO4) and perbenzoic acid in combination with such phase-transfer catalysts as benzyltriethylammonium chl
Autoxidation Reactions of Imines to form Oxaziridines and Amides
Auret, Barbara J.,Boyd, Derek R.,Coulter, Peter B.
, p. 463 - 464 (2007/10/02)
The formation of oxaziridines and the isomeric amides in equal amounts by the spontaneous autoxidation of several liquid imines via peroxyimidic acid intermediates is reported.
