204073-94-9Relevant academic research and scientific papers
Nucleophilic epoxidation of γ-alkoxy dienyl sulfoxide derivatives
Fernández De La Pradilla, Roberto,Victoria Buergo, María,Montero, Carlos,Viso, Alma
, p. 2684 - 2692 (2007/10/03)
(E,E) and (Z,E) γ-alkoxy dienyl sulfones undergo nucleophilic epoxidation with remarkable regio- and stereoselectivity to render syn oxiranes in a process mainly controlled by the alkoxy stereocenter. Upon epoxidation γ-hydroxy dienyl sulfoxides provide s
Highly diastereoselective Diels-Alder reactions with enantiopure sulfinyl-substituted 1-hydroxymethyldienes
De La Pradilla, Roberta Fernandez,Montero, Carlos,Tortosa, Mariola,Viso, Aima
, p. 5136 - 5145 (2007/10/03)
Enantiopure hydroxy-2- and -3-sulfinyldienes undergo highly selective Diels-Alder cycloadditions with various dienophiles controlled by the chiral sulfur atom. The related hydroxy-2-sulfonyldienes display complementary π-facial selectivity.
