204253-21-4Relevant academic research and scientific papers
Monomeric tripod-zinc thiolate complexes
Burth,Vahrenkamp
, p. 381 - 385 (2008/10/09)
Reaction of the pyrazolylborate-zinc complex TpCum,MeZn-OH with the corresponjjng thiols yielded the stable complexes TpCum,MeZn-SR (1: R = Ph, 2: R = CH2-Ph, 3: R = CH2-CH2-Ph) which are further representatives of this class of compounds. Using the ligand tris(benzimidazolylmethyl)amine (BIMA), zinc perchlorate, and the corresponding sodium thiolates, the cationic complexes (BIMA)Zn-SR (R = Ph, CH2Ph) were obtained, which were isolated as [(BIMA)Zn-S-Ph] BPh4 (4) and [(BIMA)Zn-S-CH2Ph] ClO4 (5). A structure determination of 4 confirmed the pseudotetrahedral coordination geometry for this new type of compounds.
