20440-21-5Relevant academic research and scientific papers
Inside-outside stereoisomerism. 5. Synthesis and reactivity of trans-bicyclo[n.3.1]alkanones prepared via the intramolecular photocycloaddition of dioxenones
Winkler, Jeffrey D.,Hong, Bor-Cherng,Hey, John P.,Williard, Paul G.
, p. 8839 - 8846 (2007/10/02)
The stereoselectivity of the intramolecular photocycloaddition of a series of bicyclic dioxenones has been examined. The selective formation of trans-fused photoadducts is observed in almost all cases, which upon fragmentation lead to the synthesis of bic
INSIDE-OUTSIDE STEREOISOMERISM III: THE SYNTHESIS OF TRANS-BICYCLODECAN-10-ONE
Winkler, Jeffrey D.,Hey, John P.,Williard, Paul G.
, p. 4691 - 4694 (2007/10/02)
The synthesis of trans-bicyclodecan-10-one, the smallest bicycloalkane to possess the inside-outside stereochemical relationship, is described, in which the trans intrabridgehead stereochemistry is established via the intramolecular dioxolenone photocycloaddition.
