204520-82-1Relevant academic research and scientific papers
Highly dissymmetric chelate coordination of 3,4,7,8-tetramethyl-1,10-phenanthroline to CuI(SR)
Stange, Andreas F.,Sixt, Torsten,Kaim, Wolfgang
, p. 469 - 470 (1998)
Not only AuI and HgII species but also CuI(SR) fragments can bind in a highly dissymmetrical fashion to symmetrical diimine chelate ligands; the 2 + 1 coordination arrangement observed for the metal in two complexes (tmphen)Cu(SR) (tmphen = 3,4,7,8-tetramethyl-1,10-phenanthroline) is characterised by obtuse angles α[N(1)-Cu-S] > 159° and by two very different distances Cu-N(1) and Cu-N(2).
