204581-99-7Relevant academic research and scientific papers
Reaction of 1,2-cyclic sulfites with some soft nucleophiles. Formation of enantiomerically pure γ-lactones
Nymann, Kirsten,Svendsen, John S.
, p. 338 - 349 (2007/10/03)
The reaction between 1,2-cyclic sulfites and soft carbon centered nucleophiles has been investigated. For monosubstituted cyclic sulfites, the main products were γ-lactones or acetoxy esters. For 1,2-disubstituted cyclic sulfites, cyclopropanes, carbonate and dioxolanes were the main products. A mechanistic rationale for the product formation is presented. Acta Chemica Scandinavica 1998.
