204637-59-2Relevant academic research and scientific papers
Thermal Si-C bond cleavage of LRhH(SiAr3)(μ-H) (μ-Cl)RhH(SiAr3)L (Ar = C6H5, C 6H4F-p; L = P(i-Pr)3) to give LRhH(μ-SiAr3)(μ-SiAr2)(μ-Cl)RhHL containing sym
Koizumi, Take-Aki,Osakada, Kohtaro,Yamamoto, Takakazu
, p. 5721 - 5727 (2008/10/08)
The reaction of dinuclear rhodium complex LRhH(SiPh3)(μ-H) (μ-Cl)RhH(SiPh3)L (1; L = P(i-Pr)3) with excess HSi(C6H4F-p)3 leads to replacement of the SiPh3 ligands with the Si-(C
A symmetrically bridging triarylsilyl ligand in a dinuclear rhodium complex: Synthesis and structure of [LRh(h) (μ-Cl) (μ-SiAr2) (μ-SiAr3) Rh(H)L] (Ar = Ph, p-FC6H4; L = PiPr3)
Osakada,Koizumi,Yamamoto
, p. 349 - 351 (2008/10/09)
Simply warming solutions of the dinuclear complexes 1 provides novel complexes 2 [Eq. (a): Ar = Ph, p-FC6H4; L = PiPr3], which contain a bridging triarylsilyl ligand and show unusual thermal stability. Compounds with this type of symmetric structure are of interest as models of the transition state for the migration of tertiary silyl groups in a bimetallic framework.
