204766-30-3Relevant academic research and scientific papers
Low-barrier pathway for endo-cleavage induced anomerization of pyranosides with N-benzyl-2,3-trans-oxazolidinone groups
Satoh, Hiroko,Hutter, Juerg,Luethi, Hans Peter,Manabe, Shino,Ishii, Kazuyuki,Ito, Yukishige
supporting information; experimental part, p. 1127 - 1131 (2009/07/11)
Pyranosides with N-benzyl-2,3-trans-oxazolidinone undergo anomerization from the β form to the α form even in the presence of a weak Lewis acid. Experimental evidence for endo-cleavage, the breaking of the bond between the pyran-oxygen and anomeric carbon
SYNTHESIS OF THE O-SPECIFIC POLYSACCHARIDE OF SHIGELLA FLEXNERI
Kotchekov, N. K.,Byramova, N. E.,Tsvetkov, Yu. E.,Backinowsky, L. V.
, p. 3363 - 3375 (2007/10/02)
A regular heteropolysaccharide built of tetrasaccharide repeating units is synthesised by means of regio- and stereospecific polycondensation of tritylated cyanoethylidene derivative.The polysaccharide obtained is identical with the O-antigenic polysaccharides of Shigella flexneri serotypes 3b, 3c, and variant Y.It also represents the basic chain of O-antigenic polysaccharides of all serotypes of this bacterium.
