204773-90-0Relevant academic research and scientific papers
Novel convenient method for the synthesis of N,N- bis(trimethylsilyloxy)enamines
Dilman,Tishkov,Lyapkalo,Ioffe,Strelenko,Tartakovsky
, p. 181 - 185 (2007/10/03)
Both primary and secondary aliphatic nitro compounds 1 were found to react with two equivalents of bromotrimethylsilane in the presence of triethylamine followed by aqueous workup to give appropriate N,N- bis(trimethylsilyloxy)enamines 3 in good isolated yields. Products 3, starting from some secondary and/or sterically hindered compounds 1, are synthesized from the corresponding silyl nitronates 2.
