204977-17-3Relevant articles and documents
Facile synthesis and photo-physical properties of cyano-substituted styryl derivatives based on carbazole/phenothiazine
Lu, Mingzhu,Zhu, Yulan,Ma, Kuirong,Cao, Li,Wang, Kun
, p. 128 - 134 (2012)
Four new cyano-substituted styryl derivatives based on carbazole and phenothiazine were facilely synthesized by conventional Knoevenagel condensation and well characterized. The UV-vis spectra of these dyes showed the lowest-energy absorption bands were mainly caused by the HOMO-LUMO one-electron promotion as conformed by TD-DFT calculations. The thermogravimetric analysis showed these dyes were thermally stable up to 350 °C. The UV-vis absorption and fluorescence emission spectra were also studied in solvents of different polarity, these dyes exhibited unusual large Stokes shift.