205041-10-7

Basic information

• Product Name: Pd(η(5)-cyclopentadienyl)(C42H49N2O6)
• CAS NO: 205041-10-7
• Molecular Weight: 849.376
• Mol File: 205041-10-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: Pd(η(5)-cyclopentadienyl)(C42H49N2O6)(CAS DataBase Reference)
• NIST Chemistry Reference: Pd(η(5)-cyclopentadienyl)(C42H49N2O6)(205041-10-7)
• EPA Substance Registry System: Pd(η(5)-cyclopentadienyl)(C42H49N2O6)(205041-10-7)

Safety Data

• Hazardous Substances Data: 205041-10-7(Hazardous Substances Data)

Upstream product

• 205041-08-3 [PdCl(C₄₂H₄₉N₂O₆)]2 
• 34822-90-7 cyclopentadienylthallium 

Relevant articles and documents

Mesomorphic cyclometalated (cclopentadienyl)palladium and -platinum complexes

The mesogenic 4,4′-bis[4-(n-octyloxy)benzoyloxy]azobenzene (HL) ligand reacts with [(PhCN)2PdCl2] to give the dinuclear cyclometalated complex [(μ-Cl)(L)Pd]2 (1), from which the mononuclear half-sandwich [(η5-C5H5)(L)Pd] (2) species has been obtained by reaction with Tl(C5H5). The PtII analogue of 2, [(η5-C5H5)(L)Pt] (4), has been prepared in a similar manner starting from [(μ-Cl)(L)Pt]2 (3), Both dinuclear complexes 1 and 3 display a smectic C phase (Sc) stable over 80°C. Whereas 4 is the first example of an 18-electron PtII mesogen, both mononuclear 2 and 4 are mesomorphic materials that exhibit a nematic phase spanning a wide temperature range.