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(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE is a complex organic compound with a unique structure that features a rhodium(I) center coordinated to a benzene and cyclooctadiene ligand. It is characterized by its orange or red crystalline powder appearance and is known for its highly efficient properties as a privileged ligand in various chemical reactions.

205064-10-4

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205064-10-4 Usage

Uses

Used in Chemical Synthesis:
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE is used as a highly efficient privileged ligand for enhancing the selectivity and reactivity of various chemical reactions, particularly in the field of homogeneous catalysis. Its unique structure and properties allow it to facilitate complex transformations with high efficiency and selectivity.
Used in Pharmaceutical Industry:
In the pharmaceutical industry, (+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE is used as a catalyst in the synthesis of complex organic molecules, including those with potential pharmaceutical applications. Its ability to improve reaction efficiency and selectivity makes it a valuable tool in the development of new drugs and active pharmaceutical ingredients.
Used in Material Science:
(+)-1,2-BIS((2S,5S)-2,5-DIMETHYLPHOSPHOLANO)BENZENE(CYCLOOCTADIENE)RHODIUM(I)TETRAFLUOROBORATE is also utilized in material science as a catalyst for the synthesis of advanced materials with specific properties, such as polymers with tailored characteristics or novel materials with unique electronic, optical, or mechanical properties. Its high efficiency and selectivity make it an attractive choice for the development of new materials with potential applications in various industries.

Reactions

The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides. Forms superior catalysts for asymmetric reductive aminations. Catalyst used for the asymmetric hydrogenation of enol phosphonates. A novel enantioselective synthesis of β-amino alcohols and 1,2-diamines. Ligand for the catalytic asymmetric [4+1] cycloaddition of vinylallenes with CO. Ligand for the Rh-catalyzed asymmetric enyne cycloisomerization. Catalytic enantioselective addition of dialkylzinc to N-Diphenylphosphinoylimines. Palladium catalyzed asymmetric phosphination.

Check Digit Verification of cas no

The CAS Registry Mumber 205064-10-4 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 2,0,5,0,6 and 4 respectively; the second part has 2 digits, 1 and 0 respectively.
Calculate Digit Verification of CAS Registry Number 205064-10:
(8*2)+(7*0)+(6*5)+(5*0)+(4*6)+(3*4)+(2*1)+(1*0)=84
84 % 10 = 4
So 205064-10-4 is a valid CAS Registry Number.

205064-10-4 Well-known Company Product Price

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  • Aldrich

  • (675539)  1,2-Bis[(2S,5S)-2,5-dimethylphospholano]benzene(cyclooctadiene)rhodium(I)tetrafluoroborate  

  • 205064-10-4

  • 675539-100MG

  • 1,705.86CNY

  • Detail

205064-10-4SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 11, 2017

Revision Date: Aug 11, 2017

1.Identification

1.1 GHS Product identifier

Product name carbanide,(1Z,5Z)-cycloocta-1,5-diene,(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-ium-1-yl]phenyl]-2,5-dimethylphospholan-1-ium,rhodium(3+),trifluoroborane,fluoride

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:205064-10-4 SDS

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