20507-33-9Relevant academic research and scientific papers
Sulfoxide-mediated Umpolung of alkali halide salts
Klimczyk, Sebastian,Huang, Xueliang,Fares, Christophe,Maulide, Nuno
, p. 4327 - 4329 (2012)
A new protocol for the direct two-electron oxidative Umpolung of alkali halide salts is reported. This procedure, relying on the use of a commercially available sulfoxide as the oxidant, allows the electrophilic halogenation of carbonyl compounds as well as halolactonisation reactions to proceed from the corresponding sodium salts, at room temperature and under mild conditions.
