2051-78-7Relevant articles and documents
Molecular recognition driven catalysis using polymeric nanoreactors
Cotanda, Pepa,O'Reilly, Rachel K.
supporting information, p. 10280 - 10282,3 (2020/09/09)
The concept of using polymeric micelles to catalyze organic reactions in water is presented and compared to surfactant based micelles in the context of molecular recognition. We report for the first time enzyme-like specific catalysis by tethering the catalyst in the well-defined hydrophobic core of a polymeric micelle.
Rhenium-Catalyzed Epoxide Deoxygenation: Scope and Limitations
Gable, Kevin P.,Brown, Eric C.
, p. 2243 - 2245 (2007/10/03)
Transfer of oxygen atoms from epoxides to triphenylphosphine is efficiently catalyzed by Tp′ReO3 [Tp′ = hydrido-tris-(3,5-dimethylpyrazolyl)borate] in benzene at 75-105 °C. The reaction tolerates a wide variety of functional groups including ketones (conjugated or non-conjugated to the new double bond), esters, nitriles, ethers, silyl ethers and phthalimides. Relative rates vary with substitution pattern and electronics; in general, monosubstituted and 2,2-disubstituted epoxides react fastest, and cis-2,3-disubstituted systems react faster than trans. Electron-withdrawing substituents promote the reaction.
ANODIC OXIDATION OF BUTYRIC ACID - THE FORMATION OF DIALKYL CARBONATES IN THE REACTION OF POTASSIUM BUTYRATE AND POTASSIUM CARBONATE IN WATER (THE HOFER-MOEST REACTION)
Brettle, Roger,Khan, M. Akram
, p. 240 - 247 (2007/10/02)
The electrolysis of potassium butyrate in water containing a large excess of potassium carbonate at a platinum anode gave, in very low yield, a mixture of ten liquid products consisting of some typical secondary products derived from propene which included 1-methylpentyl n-propyl carbonate and 2-methylpentyl n-propyl carbonate of which the latter was the major product of the electrolysis.
